Video: Nucleophiles
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Organic Reaction Hub on Instagram: "In 1965, J. Tsuji reported that π-allylpalladium chloride could be substituted with certain nucleophiles. In 1973, B.M. Trost reported that alkyl-substituted π- allylpalladium complexes could be alkylated with soft carbon nucleophiles. “Pd-catalyzed allylation of carbon nucleophiles (soft) with allylic compounds via π-allylpalladium complexes is called the Tsuji-Trost reaction” Reactivity: Hard nucleophiles (e.g., alkylithiums, alkylmagnesium halides) failed t
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